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It should be mentioned, that Rayleigh scattering always occurs, but hyper Rayleigh scattering occurs only if the scattering material does not have a center of symmetry Frequency doubled radiation consists of hyper Rayleigh scattering from a pure crystal and consequently a crystal used for frequency doubling must not have a centro symmetric unit cell The importance of the hyper Raman effect as a spectroscopic tool results from its symmetry selection rules These are determined by products of three dipole moment matrix elements relating the four levels indicated in Fig 36-1 It turns out that all infrared active modes of the scattering system are also hyper-Raman active In addition, the hyper Raman effect allows the observation of silent modes, which are accessible neither by infrared nor by linear Raman spectroscopy Hyper Raman spectra have been observed for the gaseous, liquid and solid state.

One of the earliest experiments in nuclear physics was Rutherford s demonstration of large-angle scattering of a particles by gold nuclei. This experiment established the existence of a small nucleus within the atom ( 10). The force acting in this process, called Rutherford scattering, is the repulsive Coulomb force between the positively charged nuclei. A schematic diagram of the phenomena is shown in Figure 13.6. Rutherford scattering is an elastic event, that is, no excitation of either the projectile or target nuclei occurs. However, due to conservation of energy and momentum in the interaction, the kinetic energy of the backscattered ion is less than that of the incident ion. The relation between these energies is the kinematic factor, K, which is given by the expression K 2 2 2 E1 (M2 M1 sin2 u)1=2 M1 cos u M1 M2 E0 (13:4)

However, the /tmp/ directory is still part of the operating system partition, meaning that it is still fairly easy for people who habitually use that directory to fill up the operating system partition Multiuser system Creates separate partitions for the root file system, /usr/, /var/, /tmp/, and /home/ You can choose this option when you are using this system as a server It may also be a good choice for systems that will be used by more than just you, your relatives, and your close friends The trade-off is that you may run out of room on a given partition even though the others have plenty of space, which means that you will need to plan carefully.

A full description of theory and practice of hyper-Raman spectroscopy is given by Long (1977, 1982)..

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In some situations, you may need to adjust the partition sizes selected by the multiuser partitioning scheme to put more room where you are likely to need it: If you are planning to compile a lot of large software packages, you ll need to have plenty of space in the /usr/ partition Active servers (especially Web and mail servers) may need extra room in /var/ for log files Mail servers also use this space for the mail queue, and the default mail system also stores incoming mail here (you may also want to consider making /var/mail/ a separate partition in these cases) Web browsers such as Mozilla use /tmp/ for storing files while they are downloaded This file system must be big enough to hold any large files that you want to download through there, plus any other files that may be there at the same time.

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Note that with the multiuser partitioning scheme, the /home/ partition generally ends up receiving most of the space on larger disks This usually makes it a good place to borrow space from when you want to make other partitions larger However, because partman (the partitioning tool used by the Debian installer) has already mapped out the partitions, you actually need to delete /home/ and then re-add it after you increase the size of the other partition If there are other partitions between /home/ and the one that you are increasing in size, you also need to delete them, and then add them back in an appropriate order..

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Additional startup parameters are as follows: